Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.

Lars Lauterbach; Leland B Gee; Vladimir Pelmenschikov; Francis Jenney; Saeed Kamali; Yoshitaka Yoda; Michael W W Adams; Stephen P Cramer

Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.

Lars Lauterbach, Leland B Gee, Vladimir Pelmenschikov, Francis Jenney, Saeed Kamali, Yoshitaka Yoda, Michael W W Adams, Stephen P Cramer

Department of Bio-Medical Sciences (PCOM)

Research output: Contribution to journal › Article › peer-review

Abstract

The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.

Original language	American English
Journal	Dalton transactions
State	Published - Apr 11 2016

Disciplines

Medicine and Health Sciences

Cite this

@article{0d3b141c76a64c0db5f1e25140f943df,

title = "Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.",

abstract = " The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.",

author = "Lars Lauterbach and Gee, \{Leland B\} and Vladimir Pelmenschikov and Francis Jenney and Saeed Kamali and Yoshitaka Yoda and Adams, \{Michael W W\} and Cramer, \{Stephen P\}",

year = "2016",

month = apr,

day = "11",

language = "American English",

journal = "Dalton transactions",

}

TY - JOUR

T1 - Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.

AU - Lauterbach, Lars

AU - Gee, Leland B

AU - Pelmenschikov, Vladimir

AU - Jenney, Francis

AU - Kamali, Saeed

AU - Yoda, Yoshitaka

AU - Adams, Michael W W

AU - Cramer, Stephen P

PY - 2016/4/11

Y1 - 2016/4/11

N2 - The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.

AB - The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe-4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe-4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe-S clusters.

UR - https://digitalcommons.pcom.edu/scholarly_papers/1674

M3 - Article

JO - Dalton transactions

JF - Dalton transactions

ER -

Characterization of the [3Fe-4S](0/1+) cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses.

Abstract

Disciplines

Other files and links

Cite this